Efficient Catalytic Synthesis of Xanthenes with Copper Immobilized on Amine-Modified NaY

Efficient Catalytic Synthesis of Xanthenes with Copper Immobilized on Amine-Modified NaY

Mohammadreza Azizi Amiri; Hamidreza Younesi; Haniye Kazemi Aqmashhadi; Ghasem Firouzzadeh Pasha; Sakineh Asghari; Mahmood Tajbakhsh

Volume 8, Issue 1 , December 2023, Pages 1-22

https://doi.org/10.48309/chemm.2024.424058.1737

Abstract

  The purpose of this article is to describe the synthesis of copper-amine complexes on nano NaY zeolite (Cu@NNPS-NaY), as a highly efficient, reusable, and environmentally friendly catalyst for the xanthenes synthesis. The Cu@NNPS-NaY catalyst was prepared from the reaction of silane-bonded nano NaY Zeolite (CPS-NaY) with [2-({3-[(2-aminoethyl) thio]propyl} thio)ethyl]amine (NN) followed by immobilizing copper ions onto the NNPS-NaY surface. The catalyst structure was characterized using FT-IR, XRD, TGA, EDS, DLS, SEM, TEM, ICP, and elemental analyses. The bonded long-chain amine including heteroatoms on the zeolite surface improved its catalytic activity and homogeneity, making it more capable of coordinating with copper ions. Synthesis of xanthenes was performed in the presence of Cu@NNPS-NaY catalyst (30 mg) in EtOH (10 mL) at 60 °C within 10-60 minutes resulting in product yields of 84-97%. The prepared catalyst can be easily recovered by centrifugation and reused for at least twelve consecutive runs with no significant loss of its catalytic activity. Besides the simplicity of catalyst recovery and reusing, the method is easy to set up and versatile, making it an environmentally friendly way to prepare titled heterocycles. Based on the results of this study, other useful heterocycles could be synthesized under eco-friendly conditions using this catalytic system.

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ORCID

Mohammadreza Azizi Amiri

https://orcid.org/0000-0001-8452-3762

Hamidreza Younesi

https://orcid.org/0000-0002-0738-7645

Haniye Kazemi Aqmashhadi

https://orcid.org/0009-0006-7606-7609

Ghasem Firouzzadeh Pasha

https://orcid.org/0000-0002-5054-2938

Sakineh Asghari

https://orcid.org/0000-0002-6608-9525

Mahmood Tajbakhsh

https://orcid.org/0000-0002-4856-1937

HOW TO CITE THIS ARTICLE

Mohammadreza Azizi Amiri, Hamidreza Younesi, Haniye Kazemi Aqmashhadi, Ghasem Firouzzadeh Pasha*, Sakineh Asghari. Mahmood Tajbakhsh*. Efficient Catalytic Synthesis of Xanthenes with Copper Immobilized on Amine-Modified NaY. Chem. Methodol., 2024, 8(1) 1-22

DOI: https://doi.org/10.48309/chemm.2024.424058.1737  

URL: https://www.chemmethod.com/article_185369.html

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